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E-Book

Epoxy Coatings Formulations

By the Global Formulation Team

20+ Formulations 4 Sub-categories Raw Material Profiles Manufacturing Guidelines Troubleshooting Guide
Epoxy coatings formulation handbook: two-pack anti-corrosive primers (zinc phosphate, inorganic zinc-rich 85% Zn, organic zinc-rich), high-build maintenance coatings, epoxy mastic, fast-cure systems, self-levelling epoxy floor, broadcast quartz, ESD anti-static, food-grade (FDA/EC 1935/2004), epoxy novolac tank lining (pH 0-14), bisphenol-F chemical-resistant coating, solvent-free NSF 61 lining, phenalkamine cold-cure. Part A/Part B formulations with stoichiometric mix ratios, pot life, DFT targets, QC (adhesion cross-cut/pull-off, hardness, chemical resistance). ISO 12944, SSPC, NACE/AMPP.

About this book

Epoxy Coatings Formulations is a focused technical reference for the full range of protective and industrial epoxy coating systems — anti-corrosive primers (conventional and zinc-rich), high-build industrial maintenance coatings and epoxy mastics, self-levelling and broadcast flooring systems, anti-static ESD and food-grade floor coatings, and tank linings and chemical-resistant coatings (epoxy novolac, bisphenol-F and solvent-free grades). Every formulation is a two-pack starting point structured as Part A and Part B with stoichiometrically calculated mix ratios, validated for use by coatings manufacturers, industrial flooring contractors and plant engineers.

The technology

The handbook develops epoxy resin chemistry from first principles: the bisphenol-A diglycidyl ether (BADGE) EEW–viscosity–Tg relationship, the higher chemical resistance and lower viscosity of bisphenol-F resins, and the multi-functional crosslink density of epoxy novolac for aggressive immersion service. The curing agent matrix — aliphatic and cycloaliphatic amines, polyamides (flexibility and adhesion), amidoamines (fast cure, water tolerance), Mannich base (low-temperature, phenalkamine variants), anhydrides (electrical grade) — is treated mechanistically with stoichiometry and AHEW calculation explained for each system. Zinc-rich primer cathodic protection, pigment volume concentration and zinc dust particle size are developed for both inorganic and organic zinc-rich grades. Flooring technology covers self-levelling epoxy flow and levelling, quartz-broadcast decorative systems, ESD conductive network design, and food-grade compliance. Anti-corrosion performance is framed through ISO 12944 corrosivity categories C1–Im3.

Inside the formulations

All formulations are structured as Part A (resin / pigment / extender — % w/w) and Part B (hardener — % w/w) with mix ratio, induction time, pot life at 23°C, application temperature range, DFT target, QC targets (gel time, adhesion, hardness, chemical resistance) and the stoichiometric basis for the mix ratio. Surface preparation requirements (Sa 2.5, Sa 3, SSPC-SP 6) and application conditions (ambient temperature, substrate temperature, dew point clearance) are specified for each system.

What you get

  • Two-pack epoxy formulations — Part A and Part B with stoichiometric mix ratios
  • Anti-corrosive primers: conventional zinc phosphate, inorganic zinc-rich and organic zinc-rich
  • High-build mid-coats, epoxy mastic surface-tolerant and fast-cure maintenance coatings
  • Flooring systems: self-levelling, broadcast quartz, ESD anti-static and food-grade
  • Tank linings: epoxy novolac (pH 0–14), bisphenol-F, solvent-free (NSF 61) and phenalkamine cold-cure
  • Pot life, induction time, DFT and cure schedule data for all systems
  • QC targets: adhesion (cross-cut/pull-off), hardness, MEK rub, chemical resistance
  • ISO 12944 corrosivity category selection guide and surface preparation specifications

Technical details

Format
A4 PDF · instant digital download
Scope
Anti-corrosive primers · maintenance coatings · flooring · tank linings
Chemistry
BADGE · bisphenol-F · epoxy novolac · zinc-rich · solvent-free · waterborne epoxy
Standards
ISO 12944 · SSPC · NACE/AMPP · ASTM D · ISO 2409 · ISO 4624 · NSF 61 · FDA 21 CFR
Tiers
Economy · Mid-range · Premium · Specialist
Audience
Protective coatings manufacturers · flooring contractors · plant engineers
Series
Paints & Coatings Handbook Series · Volume 3
The Problem This Solves

Epoxy coatings fail for three reasons — wrong resin-hardener stoichiometry, inadequate surface preparation and incorrect cure schedule. This handbook solves all three for every epoxy application: primers, maintenance coatings, flooring and tank linings.

Who is this book for?

Protective Coatings Manufacturer

You make anti-corrosive and protective coatings and want a technically rigorous reference for developing two-pack epoxy systems — zinc-rich primers, high-build mid-coats, epoxy mastic and fast-cure maintenance formulations — across solventborne and waterborne platforms.

Industrial Flooring Contractor

You install or supply industrial epoxy flooring and want to develop or private-label your own self-levelling, broadcast quartz, anti-static ESD and food-grade floor coating systems with verified mix ratios, cure profiles and substrate preparation standards.

Chemical Plant Engineer

You specify coatings for tank linings, pipe coatings and chemical-resistant surfaces in food, pharmaceutical, water or petrochemical plants — you need formulation-level understanding of epoxy novolac, bisphenol-F and solvent-free lining chemistry to evaluate products and diagnose failures.

What's Inside

Table of Contents

  • Bisphenol-A diglycidyl ether (BADGE) — EEW, viscosity, Tg
  • Bisphenol-F epoxy — lower viscosity, higher chemical resistance than BADGE
  • Epoxy novolac resins — high crosslink density, temperature and solvent resistance
  • Curing agent families: aliphatic amine, cycloaliphatic amine, polyamide, amidoamine, Mannich base, anhydride
  • Stoichiometry, EEW/AHEW calculation, mix ratio and pot-life control
  • Solventborne high-build epoxy anti-corrosive primer (zinc phosphate pigment)
  • Waterborne epoxy primer (BADGE emulsion + cycloaliphatic amine dispersion)
  • Inorganic zinc-rich epoxy primer (85% zinc in dry film, weldable)
  • Organic zinc-rich epoxy primer (40–60% zinc)
  • Epoxy wash primer and adhesion promoter for aluminium and galvanised steel
  • High-build epoxy mid-coat (250–300 µm DFT, barrier protection)
  • Epoxy mastic surface-tolerant coating (penetrating, wet-surface compatible)
  • Abrasion-resistant epoxy (aluminium oxide filler, DIN 53516 Taber abrasion)
  • Fast-cure low-temperature epoxy amine adduct system (5°C cure)
  • Epoxy-polyurethane hybrid topcoat (gloss retention and UV stability)
  • Self-levelling epoxy floor coating (bisphenol-A, cycloaliphatic amine, 2–3 mm DFT)
  • Broadcast quartz-aggregate decorative floor system
  • Anti-static ESD floor coating (conductive carbon and ionomer network)
  • Food-grade FDA/EC 1935/2004-compliant epoxy floor coating
  • Epoxy screed and heavy-duty floor topping (quartz-filled, 4–6 mm)
  • Epoxy novolac tank lining (solventborne, immersion grade, pH 0–14)
  • Bisphenol-F chemical-resistant coating (aromatic solvents, oxidising acids)
  • Solvent-free epoxy lining (100% solids, zero VOC, NSF 61 water contact)
  • Phenalkamine-cured epoxy for low-temperature and humid cure
  • Coal-tar epoxy for buried pipelines and marine immersion (NACE/AMPP)
  • Gel time, pot life and induction time testing (ASTM D1200, D2196)
  • DFT measurement: wet film comb and dry film gauge (SSPC-PA 2)
  • Adhesion: cross-cut (ISO 2409), pull-off (ISO 4624), bend test
  • Holiday detection and pinhole testing for lining applications
  • Failure-mode diagnosis: amine blush, solvent popping, adhesion loss, undercutting
The Handbook

See what's inside

Epoxy Coatings Formulations
The Authors

Written by practising industrial consultants

GF
The Global Formulation Team

Senior industrial chemists and process engineers with 20+ years of hands-on experience in lubricant blending, coatings formulation, cosmetics development and chemical manufacturing across Asia, the Middle East and Europe. Every formulation in this handbook has been developed and validated in real production environments — not a laboratory simulation.

Questions & Answers

Frequently asked questions

They are validated starting points. You will need to bench-test and adapt treat rates to your specific raw material lots, but you start from a working formulation — not a blank sheet.

The handbook is a PDF — high-resolution A4, printable, with bookmarks and a linked table of contents. You receive an instant download link and it is also available in your library indefinitely.

Up to 5 downloads are included with your purchase. If you need more, contact us and we will reset your download limit.

Yes. The handbook opens with a fundamentals section that explains the underlying chemistry and ingredient functions before presenting formulations — so beginners can follow the rationale, not just the recipe.

Yes. Every two-component formulation is structured as Part A (resin, pigment, extender) and Part B (hardener/curing agent) with stoichiometrically calculated mix ratios by weight and volume, induction/sweat-in time, pot life at 23°C and application window guidance.

Yes. For anti-corrosive primers and floor coatings where waterborne systems are technically viable, both waterborne (BADGE emulsion + cycloaliphatic amine dispersion) and solventborne (BADGE in aromatic/ketone solvents + polyamide hardener) formulations are provided with performance comparison notes.

Zinc-rich epoxy primers — inorganic (85% Zn in dry film) and organic (40–60% Zn) — provide cathodic protection to steel in addition to barrier effect, and are weldable without significant fume increase. Conventional epoxy anti-corrosive primers rely on barrier and inhibitive pigments (zinc phosphate, strontium chromate-free alternatives). Both are formulated in this handbook with their intended service environment defined.

Yes. A food-grade epoxy floor coating is formulated to comply with FDA 21 CFR and EU EC 1935/2004 food-contact material regulations, using non-toxic curing agents (cycloaliphatic diamine or phenalkamine), and a separate NSF 61-compliant solvent-free lining is provided for potable water contact.

Yes. Epoxy novolac (phenol-formaldehyde glycidyl ether, multi-functional EEW 170–180) provides high crosslink density for immersion in acids, alkalis, solvents and oxidising media. Bisphenol-F has lower viscosity than BADGE, enabling higher solids and thicker films without solvent. Both are formulated as tank and vessel linings with chemical resistance charts.

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